Table 5. Major- and trace-element analyses.
Major elements (wt%)
SiO2
52.51
59.46
67.52
53.68
66.15
63.50
52.56
68.13
56.85
64.78
53.80
41.37
66.25
66.61
64.63
47.74
72.93
52.68
72.11
53.29
70.46
49.41
67.83
68.80
TiO2
0.76
0.53
0.40
0.88
0.50
0.49
0.23
0.37
0.52
0.47
0.61
0.59
0.75
0.35
0.46
0.73
0.23
0.57
0.22
0.64
0.24
0.77
0.40
0.30
Al2O3
21.9
17.06
14.94
16.49
15.78
15.64
7.76
4.52
17.28
16.51
14.93
17.01
13.90
15.39
15.57
18.37
14.17
16.17
14.40
16.65
15.13
18.29
14.37
15.17
FeOt
6.23
6.35
3.89
8.11
3.80
5.14
9.99
1.19
5.27
3.16
7.88
7.86
5.11
4.70
4.72
8.22
1.76
8.13
1.94
7.14
2.25
7.85
4.11
2.81
MnO
0.04
0.04
0.05
0.16
0.06
0.11
0.21
0.14
0.10
0.05
0.11
0.05
0.08
0.05
0.04
0.13
0.01
0.12
0.02
0.05
0.04
0.07
0.07
0.05
MgO
2.00
1.72
1.38
5.46
2.68
3.43
13.04
1.86
6.48
1.32
4.52
3.49
2.01
1.22
2.33
8.29
0.48
10.93
0.48
8.99
1.44
6.48
2.63
1.68
CaO
9.43
6.72
3.64
9.51
4.13
4.47
11.42
11.73
3.35
4.48
5.01
7.43
5.39
4.24
5.01
4.61
1.70
0.98
1.72
0.74
2.77
10.56
2.92
2.82
Na2O
3.43
2.84
3.33
2.65
2.58
2.32
1.20
2.26
3.14
2.79
2.90
2.73
0.86
3.84
2.90
2.07
3.57
3.58
3.61
0.83
2.48
2.70
2.76
2.59
K2O
0.41
2.57
3.15
0.34
2.76
1.68
0.37
0.22
1.80
3.88
3.58
0.55
2.26
1.22
1.99
1.97
4.62
0.07
4.60
4.39
3.86
0.28
1.65
3.89
P2O5
0.156
0.264
0.174
0.086
0.087
0.072
0.023
0.079
0.065
0.103
0.097
0.329
0.138
0.096
0.077
0.076
0.067
0.055
0.066
0.049
0.081
0.147
0.051
0.089
H2O
2.02
1.25
0.94
1.84
2.14
2.59
2.13
0.43
4.50
1.10
—
3.21
1.53
—
1.75
6.21
0.53
6.06
0.32
6.22
0.95
2.06
2.48
1.19
CO2
0.09
0.11
0.18
0.13
0.14
0.74
0.12
9.88
1.20
0.75
—
0.40
1.15
—
0.26
1.46
0.03
0.13
0.02
0.23
0.06
0.18
0.08
0.13
Total
98.98
98.91
99.59
99.34
100.81
100.18
99.05
100.81
100.56
99.39
93.44
85.02
93.43
97.72
99.74
99.88
100.10
99.48
99.51
99.22
99.76
98.80
99.35
99.52
Trace elements (ppm)
Ba
93
717
912
108
369
268
12
45
133
345
748
336
312
105
198
92
880
<8
897
36
168
82
65
208
Rb
9
90
117
15
106
36
8
9
25
140
48
9
108
69
86
19
167
<4
171
20
245
<4
11
225
Sr
298
326
268
163
124
95
28
515
88
145
139
436
201
126
99
104
187
61
194
55
82
385
66
91
Pb*
3.45
4.38
4.82
4.87
6.95
3.34
0.415
3.92
4.79
15.5
4.49
4.89
27.9
3.55
9.26
9.00
12.68
2.01
13.2
2.30
65.9
2.60
1.53
57.1
Th*
4.27
14.1
24.3
0.925
10.7
3.61
0.096
8.54
2.24
8.92
6.46
12.7
11.9
2.95
2.66
1.37
18.6
0.233
19.2
0.365
8.48
6.58
0.757
9.84
U*
1.22
4.72
7.21
0.463
1.99
0.822
0.087
1.64
1.48
2.33
0.332
3.16
2.85
1.14
0.737
1.09
6.59
0.376
6.95
2.07
2.48
3.18
0.619
3.06
Zr
73
100
157
70
131
87
16
325
62
121
127
64
216
93
100
53
178
30
177
32
74
83
81
88
Hf*
2.29
3.02
4.39
1.47
1.05
2.53
0.374
1.78
1.54
0.616
2.18
2.22
5.40
2.77
1.04
1.78
3.21
0.683
3.06
0.993
0.826
2.56
2.10
0.680
Nb*
3.37
6.92
8.78
2.60
8.08
2.63
0.291
6.32
1.78
7.51
6.07
5.19
11.2
2.07
2.87
2.45
10.5
0.449
11.1
0.556
10.4
3.91
0.819
9.97
Ta*
0.272
0.510
0.621
0.194
0.680
0.210
0.025
0.439
0.175
0.650
0.508
0.386
0.920
0.149
0.235
0.159
0.968
0.039
0.981
0.043
1.70
0.330
0.068
1.50
Y*
16.1
13.8
18.7
18.2
19.3
17.1
8.03
16.4
17.0
16.0
17.4
23.9
30.0
23.4
14.5
17.8
17.4
7.34
22.3
17.8
10.7
20.9
18.0
13.8
La*
12.2
23.6
25.4
3.27
29.3
8.75
0.355
24.2
6.24
25.6
12.2
32.1
36.6
8.84
11.4
5.83
44.3
0.464
48.1
2.44
13.3
12.6
3.00
17.6
Ce*
27.2
46.9
53.4
9.31
58.1
18.3
1.00
54.4
12.6
52.0
22.2
67.8
75.6
19.7
22.5
13.3
88.6
1.39
96.0
6.70
28.2
39.7
8.16
36.7
Pr*
3.71
5.62
6.64
1.49
6.59
2.26
0.177
6.79
1.62
6.11
3.21
8.56
8.44
2.72
2.65
1.85
10.0
0.245
11.0
1.11
3.26
4.06
1.31
4.28
Nd*
15.2
21.7
26.1
7.28
24.0
8.95
1.00
26.1
6.87
22.4
13.3
33.2
33.1
12.0
10.1
8.11
35.4
1.41
39.0
5.85
11.8
17.3
6.50
15.7
Sm*
3.80
4.36
5.33
2.36
4.82
2.33
0.515
5.05
2.04
4.78
3.11
7.28
6.19
3.23
2.39
2.39
6.58
0.571
7.19
2.12
2.95
4.60
2.19
3.67
Eu*
1.10
1.05
1.14
0.830
1.05
0.604
0.159
0.863
0.642
0.967
0.870
1.55
1.20
0.961
0.675
0.676
1.16
0.227
1.28
0.689
0.628
1.20
0.573
0.660
Gd*
3.66
3.45
4.18
2.92
4.31
2.63
0.827
3.90
2.54
4.08
3.11
6.12
6.66
3.57
2.53
2.85
5.01
0.838
5.69
2.65
2.66
4.60
2.52
3.30
Tb*
0.598
0.501
0.617
0.541
0.668
0.480
0.186
0.595
0.475
0.619
0.520
0.917
0.905
0.637
0.450
0.534
0.714
0.177
0.832
0.497
0.419
0.755
0.472
0.521
Dy*
3.47
2.80
3.54
3.56
3.84
3.17
1.35
3.26
3.17
3.38
3.32
5.10
4.97
4.09
2.80
3.49
3.76
1.32
4.50
3.39
2.23
4.46
3.13
2.89
Ho*
0.666
0.550
0.718
0.753
0.748
0.677
0.312
0.624
0.681
0.624
0.707
0.963
1.04
0.886
0.578
0.742
0.708
0.312
0.868
0.748
0.402
0.846
0.687
0.529
Er*
1.72
1.52
2.09
2.11
2.03
1.97
0.924
1.68
1.92
1.61
2.13
2.44
2.62
2.57
1.60
2.08
1.90
0.955
2.39
2.20
1.09
2.16
2.03
1.45
Tm*
0.234
0.228
0.332
0.315
0.297
0.312
0.151
0.248
0.301
0.222
0.371
0.320
0.387
0.404
0.240
0.321
0.271
0.156
0.355
0.338
0.163
0.286
0.327
0.218
Yb*
1.41
1.55
2.31
2.04
1.86
2.15
1.03
1.61
1.98
1.39
2.99
1.89
2.61
2.70
1.59
2.10
1.76
1.06
2.34
2.26
1.08
1.68
2.26
1.36
Lu*
0.188
0.234
0.361
0.297
0.269
0.332
0.165
0.238
0.304
0.191
0.514
0.258
0.368
0.424
0.240
0.309
0.250
0.157
0.343
0.346
0.152
0.228
0.354
0.196
V
229
163
61
230
100
124
208
19
165
104
157
224
107
39
115
232
18
233
17
272
44
262
112
57
Cr
<18
<18
<18
<18
40
19
207
<18
117
<18
54
33
75
<18
<18
47
<18
130
<18
124
<18
176
<18
<18
Co
10
13
6
32
12
14
47
<4
13
7
15
14
19
6
14
64
<4
35
<4
25
7
20
13
8
Ni
<2
3
11
15
4
<2
139
<2
28
3
11
18
29
<2
<2
51
<2
44
<2
60
3
26
<2
<2
Cu
50
26
11
13
17
15
37
<4
22
11
22
120
22
10
47
76
<4
28
<4
116
16
48
39
8
Zn
69
57
37
63
33
98
41
18
94
41
64
115
86
146
53
87
21
93
16
44
42
63
55
41
Ga
20
16
16
13
19
16
11
<8
17
21
16
12
21
18
17
17
20
11
23
21
13
22
16
18
Notes: Data from ICP-MS is denoted with *, all other data from XRF. ICP-MS data reflect averages of duplicate analyses. — = no data available.