Table 3. Calculated gas to water volumetric ratios and gas to gas hydrate volumetric ratios expected from dissociated Structure I gas hydrate containing only methane at conditions expected at the Blake Ridge (22-32 MPa), as compared to gas hydrate equilibrium pressures at 1 MPa.
Location | Site/Hole | Depth (mbsf) |
Gas
to water volume ratio |
Gas to water volume ratio (chlorinity correction) | Chlorinity (mM) | Reference |
---|---|---|---|---|---|---|
Blake Ridge |
533A |
238 |
20 |
NA |
Kvenvolden and Barnard, 1983 |
|
Middle America Trench |
565 |
319 |
133 |
137 |
15 |
Kvenvolden et al., 1984 |
Offshore Costa Rica |
568 |
404 |
30 |
36 |
92 |
|
568 |
404 |
7 |
8 |
89 |
||
570 |
192 |
4? |
NA |
|||
570 |
192 |
29 |
30 |
19 |
||
570 |
192 |
29 |
30 |
19 |
||
570 |
259-268 |
24-42 |
NA |
|||
570 |
273 |
12 |
NA |
|||
Gulf of Mexico* |
Green Canyon* |
<5 |
152 |
NA |
Davidson et al., 1986 |
|
Green Canyon* |
1-1.5 |
70 |
94 |
138 |
Brooks et al., 1984 |
|
Green Canyon* |
70 |
102 |
169 |
|||
Green Canyon-184* |
70 |
NA |
Brooks et al., 1989 |
|||
Green Canyon-204* |
85 |
NA |
||||
Green Canyon-234* |
177 |
NA |
||||
Garden Banks-388 |
68 |
NA |
||||
Green Canyon-257 |
35 |
NA |
||||
Green Canyon-320 |
66 |
NA |
||||
Offshore Peru |
685A |
165.6 |
100 |
111 |
51.4 |
Kvenvolden and Kastner, 1990 |
688A |
141 |
13 |
16 |
90.6 |
||
688A |
141 |
20 |
35 |
232.3 |
||
Cascadia, offshore Oregon | 892D |
18 |
70 |
81** |
NA |
Lorenson and Kastner, unpublished data |
892D |
18 |
53 |
62** |
NA |
Notes: NA = not analyzed. * = structure II gas hydrate is likely though not confirmed; maximum gas to water ratio is 220, ** = calculated pore-water dilution of 14% from oxygen isotopic shift between gas hydrate water and pore water. Maximum values in nature are expected to be about 195-204. Values less than these reflect partial decomposition during core recovery. Values range from 4 to 177. A chlorinity correction made to some ratios using the nearest sediment pore-water concentration results in a revised range of 8-137.