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Table 3. Calculated gas to water volumetric ratios and gas to gas hydrate volumetric ratios expected from dissociated Structure I gas hydrate containing only methane at conditions expected at the Blake Ridge (22-32 MPa), as compared to gas hydrate equilibrium pressures at 1 MPa.
 
Location Site/Hole Depth
(mbsf)
Gas to water
volume ratio
Gas to water volume ratio (chlorinity correction) Chlorinity (mM) Reference

Blake Ridge

533A

238

20



NA

Kvenvolden and Barnard, 1983

Middle America Trench

565

319

133

137

15

Kvenvolden et al., 1984

Offshore Costa Rica

568

404

30

36

92





568

404

7

8

89





570

192

4?


NA





570

192

29

30

19





570

192

29

30

19





570

259-268

24-42


NA





570

273

12


NA



Gulf of Mexico*

Green Canyon*

<5

152


NA

Davidson et al., 1986



Green Canyon*

1-1.5

70

94

138

Brooks et al., 1984



Green Canyon*



70

102

169





Green Canyon-184*



70


NA

Brooks et al., 1989



Green Canyon-204*

85



NA







Green Canyon-234*



177


NA





Garden Banks-388



68


NA





Green Canyon-257



35


NA





Green Canyon-320



66


NA



Offshore Peru

685A

165.6

100

111

51.4

Kvenvolden and Kastner, 1990



688A

141

13

16

90.6





688A

141

20

35

232.3


Cascadia, offshore Oregon
892D

18

70

81**

NA
Lorenson and Kastner, unpublished data

892D

18

53

62**

NA

Notes: NA = not analyzed. * = structure II gas hydrate is likely though not confirmed; maximum gas to water ratio is 220, ** = calculated pore-water dilution of 14% from oxygen isotopic shift between gas hydrate water and pore water. Maximum values in nature are expected to be about 195-204. Values less than these reflect partial decomposition during core recovery. Values range from 4 to 177. A chlorinity correction made to some ratios using the nearest sediment pore-water concentration results in a revised range of 8-137.

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