Figure 6. Measured pore-water (open hexagons) compositions
and hydrate meltwater compositions for samples from depths shallower than 3.5
mbsf (filled squares) and greater than 32 mbsf (open squares). Curves labeled 1,
2, and 3 are FRI-curves determined with lower boundary conditions, with [Cl-]
and 2H
of 1400 and -5.6, 1220 and -5.6, and 1220 and -6.0, respectively. The principle
for determination of hydrate amount (see "Appendix B" in Chap.
22, this volume) is demonstrated by vector V, which shows how the
composition of a pore-water sample with an initial composition on FRI-curve 2
will change when mixed with hydrate meltwater. The slope of vector V can be
calculated from the initial composition of the pore water ("Appendix
B" in Chap. 22, this
volume). Hydrate amount is determined by decomposition of the vector V that
intersects a particular pore-water or hydrate meltwater composition into vectors
V1 and V2. Vector Va was used to determine the
composition of the shallow hydrate samples. The composition of the deepest
hydrate sample was determined by the means of vector Vb.