CONCLUSIONS
- The shallow, vertical pore-water gradients observed along the
Bahamas Transect are thought to be influenced primarily by differences in
sediment reactivity, possibly induced by changes in sedimentation rates and
strong bottom currents active since the late Pliocene.
- Pore-fluid profiles in the lower Pliocene-Miocene sequences are
dominated by diffusion and do not show significant evidence of subsurface
advective flow. Deeper interstitial waters are believed to be the in situ
fluids that have evolved mainly through interactions with sediments.
- The increase in Na+ and Cl- content
observed with depth is postulated to result from the expulsion of Na+
and Cl- into pore waters during alteration of metastable
aragonite and HMC to LMC and dolomite. It is also possible that some of the
increase is caused by upward diffusion of salt from Early Jurassic
evaporites.
- Pore-fluid chemistry is dominated by the influences of carbonate
recrystallization, much of which is thought to occur soon after deposition
during open exchange with bottom water. Extensive later stage burial
diagenesis of carbonate is limited to zones of sulfate-reduction reactions,
where enhanced carbonate dissolution occurs.
- Marginal sites are characterized by alternations between
sulfate-reducing and non-sulfate-reducing zones, which are controlled by the
availability of labile organic matter and sulfate. Sulfate availability in
deeper sediments is controlled by sulfur cycling pathways and the presence
or absence of dissolved Fe2+. Interfaces between sulfate-reducing
and non-sulfate-reducing zones are sites of ongoing reaction and
precipitation of minerals such as celestite and barite.