12. LATE QUATERNARY RECORDS OF ORGANIC CARBON, CALCIUM CARBONATE, AND BIOMARKERS FROM SITE 1016 OFF POINT CONCEPTION, CALIFORNIA MARGIN1

Masanobu Yamamoto,2 Masumi Yamamuro,3 and Ryuji Tada4

ABSTRACT

Total organic carbon (TOC) and calcium carbonate (CaCO3) concentrations were determined for 304 samples, and biomarkers were analyzed for 101 samples from Core 167-1016C-1H. TOC varies between 1% and 2%, and CaCO3 is typically 1%-4%, with peaks reaching 14%.

Paleotemperature estimated from varies from 8.5° to 17.5°C. The variation implies that Core 167-1016C-1H covers oxygen isotope Stages 1-6.

Peaks of diatom-derived C25:1 HBI alkene concentrations occur during warming intervals, suggesting intensified upwelling during deglaciation. The concentrations of haptophyte-derived alkenones and diatom-derived C25:1 HBI alkene vary out of phase, which presumably resulted from the changes in the mode of nutrient supply to surface mixed layer.

Maximal CaCO3 contents (>10%) were observed in both warming and cooling intervals. The peak in cooling interval relates to an alkenone maximum, whereas the peaks in warming intervals do not. This implies that carbonate production is not the only factor controlling carbonate compensation depth at this site, and it suggests considering the changes in North Pacific deep-water chemistry.

Petroleum-type compounds are present in Site 1016 sediments. Their concentrations are maximized in the warming intervals that correspond to the timing of destruction of a huge tar mound off Point Conception. The tarry material was presumably transported by the Arguello Fan system to Site 1016.

1Lyle, M., Koizumi, I., Richter, C., and Moore, T.C., Jr. (Eds.), 2000. Proc. ODP, Sci. Results, 167 [Online]. Available from World Wide Web: <http://www-odp.tamu.edu/publications/167_SR/167sr.htm>. [Cited YYYY-MM-DD]

2Mineral and Fuel Resources Department, Geological Survey of Japan, 1-1-3 Higashi, Tsukuba, Ibaraki 305-8567, Japan. yamamoto@gsj.go.jp

3Marine Geology Department, Geological Survey of Japan, 1-1-3 Higashi, Tsukuba, Ibaraki 305-8567, Japan.

4Geological Institute, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113, Japan.

Date of initial receipt: 14 October 1998
Date of acceptance: 15 June 1999
Ms 167SR-224

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