Table 3. Interstitial water chemical signatures of organic matter diagenesis.
Site name (latitude) | Site | Water depth* (m) |
Distance from shore (km) |
Depth range of IW sampling (mbsf) | Sulfate "zero" depth† (mbsf) |
Alkalinity maximum |
|
Phosphate maximum |
|
Ammonium maximum | |||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Concentration
(mM)
|
Depth
(mbsf) |
|
Concentration
(mM)
|
Depth
(mbsf) |
|
Concentration
(mM)
|
Depth
(mbsf) |
||||||
Gorda Transect (~40°N): | |||||||||||||
Eel River Basin‡ | 1019 | 989 | 59 | 242 | 13 | 95 | 78-147 | >340 (to 400) | 61-137 | >13 | 165 | ||
Delgada Slope | 1022 | 1927 | 87 | 161 or 326** | 37 | >15 | 37-161 | >65 | 28-47 | 5.7 | 161 (still increasing) | ||
Eastern flank, Gorda Ridge | 1020 | 3050 | 167 | 260 | 107 | 20 | 31-136 | 55 | 12-50 | >3 | 164-193 | ||
Outer Delgada Fan | 1021 | 4215 | 364 | 305 | — | 9 | 136-165 | >15 | 3-79 | >0.5 | 79-189 | ||
Conception Transect (~35°N): | |||||||||||||
Santa Lucia Slope | 1017 | 967 | 52 | 180 | 19 | >40 | 19-48 | >100 (to 161) | 10-48 (at 19) | 8.5 | 76-180 | ||
Pelagic site, off Point Conception | 1016 | 3846 | 148 | 274 | 79 | >17 | 40-50 | 57 | 31-40 | 2.3 | 79-274 | ||
Baja Transect (~30°N): | |||||||||||||
Animal Basin | 1011 | 2033 [~1600] | 85 | 247 | 41†† | >20 | 30-90 | >40 | 10-60 | >2.5 | 50-150 | ||
Ocean crust, near Guadalupe Island | 1010 | 3465 | 209 | 170 | — | >4 | 50 | Always <10 | — | 0.13 | 170 | ||
Coastal Transect (other sites): | |||||||||||||
Sediment drift, south of Guide Seamount (~37°N) | 1018 | 2476 | 76 | 402 | 9 | >50 | 19-76 | >165 (to 182) | 19-47(at 38) | >6.5 to 7.5104-257 | |||
Tanner Basin (~33°N) | 1014 | 1177 [1165] | 155 | 444 | 17 | >100 | 137-222 | >150 (up to 200) | 27-191 (108-137) | >35 | 347-444 | ||
San Nicolas Basin (~33°N) | 1013 | 1575 [1106] | 115 | 131 | 27 | >50 | 46 | >170 | 19 | >13 | Increasing throughout | ||
East Cortes Basin (~32°N) | 1012 | 1783 [1415] | 105 | 267 | 19 | 67 | 162 | 100 | 7-38 | >14 | 131 |
Notes: Site numbers in bold in the onshore-offshore transects indicate sites that are also part of the north-south Coastal Transect. * = numbers in brackets indicate basin sill depth. IW = interstitial waters. † = depth of the shallowest sample with nondetectable sulfate concentrations (generally <1 mM). ‡ = this site has major decreases in chlorinity, salinity, and sodium in its interstitial water (IW) profiles; see site chapters in Lyle, Koizumi, Richter, et al. (1997). ** = samples from below 161 mbsf for Site 1022 were analyzed shipboard only for alkalinity, pH, and salinity, because of time limitations imposed by the end of the cruise. †† = sulfate increases again at depth at this site.