7. Sulfide Mineral Chemistry and Petrography and Platinum Group Element Composition in Gabbroic Rocks from the Southwest Indian Ridge1

D. Jay Miller2, 3 and Pablo Cervantes2, 3

ABSTRACT

Ocean Drilling Program (ODP) Leg 176 built upon the work of ODP Leg 118 wherein the 500-m section that was sampled represented the most complete recovery of an intact portion of lower oceanic crust ever described. During Leg 176, we deepened Hole 735B to >1500 m below seafloor in an environment where gabbroic rocks have been tectonically exposed at the Southwest Indian Ridge. This new expedition extended the remarkable recovery (>85%) that allowed unprecedented investigations into the nature of the lower oceanic crust as a result of Leg 118. Sulfide mineral and bulk rock compositions were determined from samples in the 1000-m section of oceanic gabbros recovered during Leg 176. The sulfide assemblage of pyrrhotite, chalcopyrite, pentlandite, and troilite is present throughout this section, as it is throughout the 500-m gabbroic section above that was sampled during Leg 118. Troilite is commonly present as lamellae, and the only interval where troilite was not observed is from the uppermost 150 m of the section sampled during Leg 118, which is intensely metamorphosed. The common presence of troilite indicates that much of the sulfide assemblage from Hole 735B precipitated from a magmatic system and subsequently underwent low-temperature reequilibration. Evaluation of geochemical trends in bulk rock and sulfides indicates that the combined effects of olivine accumulation in troctolites and high pentlandite to pyrrhotite ratios account for the sporadic bulk rock compositions high in Ni. Bulk rock and sulfide mineral geochemical indicators that are spatially coincident with structural and physical properties anomalies indicate a heretofore unrecognized lithologic unit boundary in this section. Platinum-group element (PGE) compositions were also determined for 36 samples from throughout the section that were recovered during Leg 176. Whereas most samples had low (<0.4 ppb) PGE concentrations, rare samples had elevated PGE values, but no unique common trend between these samples is evident.

1Miller, D.J., and Cervantes, P., 2002. Sulfide mineral chemistry and petrography and platinum group element composition in gabbroic rocks from the Southwest Indian Ridge. In Natland, J.H., Dick, H.J.B., Miller, D.J., and Von Herzen, R.P. (Eds.), Proc. ODP, Sci. Results, 176 [Online]. Available from World Wide Web: <http://www-odp.tamu.edu/publications/176_SR/chap_07/chap_07.htm>. [Cited YYYY-MM-DD]

2Department of Geology and Geophysics, Texas A&M University, College Station TX 77845, USA.

3Ocean Drilling Program, Texas A&M University, 1000 Discovery Drive, College Station TX 77845-9547, USA. Correspondence author: miller@odpemail.tamu.edu

Initial receipt: 24 August 2000
Acceptance: 17 December 2001
Web publication: 6 August 2002
Ms 176SR-009

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