LITHOSTRATIGRAPHY

Introduction

Nearly 286 m of sediments and sedimentary rocks above a contact with a basement of metamorphic rocks was cored in Hole 1114A. Seven lithostratigraphic units are recognized on the basis of sediment or rock type, grain size, sedimentary structure, color, compositions determined in smear slides and thin sections, bulk mineralogy (X-ray diffraction [XRD]), and carbonate determinations. The recovery was poor, and geophysical logs (especially FMS) were useful to help reconstruct the succession.

The lithostratigraphic units recognized are shown in Figure F1, and a bed-by-bed log is shown in Figure F2. Unit I is a surficial, soft pelagic and hemipelagic ooze and clay. By contrast, all the underlying units are at least partly lithified. Unit II consists mainly of siltstone to claystone. Unit III, by far the thickest, is composed of intercalated sandstone, siltstone, and claystone. Two subunits are recognized within Unit III: (1) Subunit IIIA is a thin interval of calcite-cemented siltstone and sandstone and very minor limestone (packstone) and (2) Subunit IIIB is distinguished by the presence of minor granule conglomerates. In Unit IV, the sandstones change to an unusual dusky red color. Below this is a thin interval of finer grained silty claystone forming Unit V underlain by a tectonic breccia (Unit VI) that overlies metadolerite (see "Igneous and Metamorphic Petrology").

Lithostratigraphic Unit I

Description: clay-bearing nannofossil ooze
Interval: 180-1114A-1R-1, 0-37 cm
Depth: 0.0-0.37 mbsf
Age: Pleistocene

Lithostratigraphic Unit I is represented by only 37 cm in Section 1R-1 in which the following sediment types are present.

Foraminifer-Bearing Nannofossil Ooze and Clay

This is pale, homogeneous, fine-grained ooze and clay, with scattered foraminifers and rare laminations rich in planktonic foraminifers (e.g., interval 180-1114A-1R-1, 7-32 cm). A calcium carbonate analysis of Sample 180-1114A-1R, 15-16 cm, indicates a value of 65 wt%. In smear slides, the calcareous clay contains rare quartz, volcanic glass (colorless and brown), opaque minerals, planktonic foraminifers, calcareous nannofossils, radiolarians, and sponge spicules (see "Site 1114 Smear Slides"). The XRD analyses reveal the presence of only calcite and minor plagioclase within one sample of foraminifer-bearing nannofossil ooze (Table T3).

Silt

Silts observed in smear slides are made up of quartz, plagioclase, volcanic rock fragments, volcanic glass (partly devitrified), and carbonate grains together with rare accessory minerals (pyroxene and amphibole), pyrite, and sponge spicules (see "Site 1114 Smear Slides"). Common planktonic foraminifers, nannofossils, and rare sponge spicules are also present. An impregnated thin section contains quartz, plagioclase, basaltic lithoclasts, altered acidic grains, devitrified glass, hornblende, pyroxene, organic-rich (plant?) material, and rare planktonic foraminifers set in a clay-rich matrix (see "Site 1114 Thin Sections"). In addition, occasional thin interbeds of silt contain small angular intraclasts (several millimeters) of indurated quartz-rich siltstone (e.g., interval 180-1114A-1R-1, 32-37 cm).

Sand

There are occasional thin beds of foraminifer sand with rare detrital material. In smear slides, this sediment contains, in addition to planktonic foraminifers and calcareous nannofossils, rare quartz, volcanic glass, opaque grains, calcite grains (undifferentiated), radiolarians, and sponge spicules (see "Site 1114 Smear Slides").

Pebbles

Small (several centimeters), angular pebbles of quartz-rich siltstone are found just above the contact with the underlying lithified sediment (Unit II; e.g., interval 180-1114A-1R-1, 32-37 cm).

Interpretation

Lithostratigraphic Unit I is interpreted as calcareous pelagic and hemipelagic sediment that accumulated during the Pleistocene at a middle bathyal water depth (500-2000 m) (see "Biostratigraphy"). There is an abrupt change from soft pelagic and hemipelagic ooze and clay of Unit I to well-lithified sedimentary rocks of Unit II, which is interpreted as an unconformity (see "Lithostratigraphic Unit II"). Nannofossil Subzones NN19E and NN19F are missing (see "Biostratigraphy"); possible reasons are discussed in the concluding depositional history discussion. The planktonic foraminifer-rich sands may record episodes of relatively high productivity or be caused by winnowing of the clay fraction. The silts contain fine-grained volcaniclastic sediment, including altered volcanic lithoclasts and glass. Similar volcaniclastic material is strewn through the background pelagic and hemipelagic sediments. Recovery was inadequate to more fully document depositional processes.

Lithostratigraphic Unit II

Description: siltstone to claystone
Interval: Cores 180-1114A-2R through 6R
Depth 6.6-55.0 mbsf
Age: late Pliocene-Pleistocene

Lithostratigraphic Unit II is marked by an abrupt change from soft sediment to much less calcareous lithified claystone to siltstone.

Claystone

The claystone is dark green and structureless with Chondrites burrows imparting a slight color mottling. The claystone is locally silty or sandy and both silt- and sand-filled burrows are present. Determinations of calcium carbonate content indicate values ranging from 3.1 to 4.4 wt% (see "Organic Geochemistry"). Smear slides show that the claystone is rich in nannofossils with rare quartz, feldspar, biotite, clay, colorless volcanic glass, accessory minerals, calcite, and planktonic foraminifers (see "Site 1114 Smear Slides"). Silty claystones contain rare foraminifer tests and detrital sand grains. The XRD analysis of a silty claystone (Sample 180-1114A-5R-1, 17-18 cm; see Table T3), indicates the presence of major plagioclase and quartz, and minor pyroxene, chlorite, amphibole, and illite. The XRD analysis of a claystone (Sample 180-1114A-6R-2, 4-4.5 cm; see Table T3) indicates the presence of major plagioclase and minor quartz, pyroxene, and illite.

Siltstone

Siltstones occur either as homogenous intervals (several tens of centimeters thick) or as thin beds or partings. The siltstone is slightly calcareous, based upon reaction with dilute HCl. The unit is characterized by repetitive intercalations of siltstone and claystone. For example, nine such transitions were noted in Section 3R-2. Several of the silts grade into silty clay, but the base of the beds can rarely be observed owing to drilling disturbance. Where preserved, the bases of the beds are sharp. Partings exhibit diffuse tops and bases (e.g., interval 180-1114A-3R-1, 49-52 cm). These partings are mainly structureless and poorly sorted with angular fine-sand grains, including quartz, feldspar, rock fragments, and accessory minerals (pyroxene and amphibole). The rock is locally tectonically deformed (see "Structural Geology").

In smear slides, the clayey silts were observed to contain common quartz, clay, and nannofossils, and rare feldspar, biotite, volcanic rock fragments, volcanic glass (mainly colorless), accessory minerals, calcite, planktonic foraminifers, and sponge spicules (see "Site 1114 Smear Slides").

Sandstone

Very thin beds of fine-grained sandstone exhibit sharp, scoured bases and gradational tops (e.g., interval 180-1114-3R-1, 57-58 cm). Several medium beds (<20 cm) of fine-grained sandstone grade up into siltstone, then silty claystone (e.g., interval 180-1114A-2R-2, 42-60 cm). Sharp bases are rarely preserved (e.g., Section 6R-1). A possible reason is that these intervals were more sand rich and were commonly not recovered by drilling. In one instance, fine-planar lamination was noted (i.e., interval 180-1114A-5R-1, 68-93 cm; see Fig. F3). The relative abundance of fine- to medium-grained sandstone increases toward the base of the unit (i.e., Section 5R-1).

In smear slides, the sandstones contain feldspar, quartz, and reddish altered rock fragments (see "Site 1114 Smear Slides"). In addition, two thin sections contain unaltered plagioclase, quartz, planktonic foraminifers, muscovite, basaltic and acidic rock fragments, and phosphatic grains (Fig. F4). A small number of grains of polycrystalline quartz were observed (see "Site 1114 Thin Sections"). XRD analysis additionally reveals the presence of plagioclase, quartz, hornblende, pyroxene, calcite, rare chloritic grains, vesicular glass, and opaque grains set in a carbonate cement (Table T3).

Interpretation

Lithostratigraphic Unit II records argillaceous hemipelagic sediment interspersed with siltstone and fine to rare medium-grained sandstone, interpreted as turbidites. The benthic foraminifer assemblage indicates middle bathyal water depths (see "Biostratigraphy"). The silty claystone, siltstone, and sandstone all contain similar volcaniclastic sediment assumed to have been derived from a calc-alkaline source area, in view of the nature of the mineral grains (mainly quartz, plagioclase, biotite, and amphibole). Compared to Unit I, there were marked increased detrital constituents, as opposed to calcareous pelagic sediment, including plankton, either because of a decrease in primary productivity or because of dilution by increased volcaniclastic input. Also, the calcium carbonate content is greatly diminished (see "Organic Geochemistry"), reflecting the decreased abundance of nannofossils in Unit II compared to Unit I. However, bottom conditions remained oxidizing in view of the presence of Chondrites burrows.

Lithostratigraphic Unit III

Description: sandstone, siltstone and claystone
Interval: Cores 180-1114A-7R through 25R, except for Subunit IIIA (14R-1, 80 cm, through 15R-CC) and Subunit IIIB (20R-1, 0-60 cm)
Depths: 55.0-237.6 mbsf, except for 123.2-141.6 mbsf (Subunit IIIA) and 180.1-180.7 mbsf (Subunit IIIB)
Age: late Pliocene to middle Pliocene

Lithostratigraphic Unit III makes up the greater part of the succession in Hole 1114A, although the recovery was very poor (Fig. F1). However, the missing intervals were reconstructed by using geophysical log and FMS data. In addition, two thin distinctive intervals were recovered. Subunit IIIA is composed of calcite-cemented siltstone and sandstone and minor limestone (packstone), mainly composed of bioclasts. Subunit IIIB, lower in the section, is composed of conglomerate and sandstone.

The following lithologies are present in decreasing order of abundance: sandstone, siltstone, and claystone.

Sandstone

Abundant sandstone varies from weakly to strongly calcareous. The sandstones are mainly fine to medium grained, but locally coarse grained (e.g., interval 180-1114A-24R-1, 7-11 cm). Colors are predominantly dark gray to locally dark greenish gray in the upper part, but then change to brown to reddish brown in the lower part of the succession (i.e., below Core 15R).

Many of the sandstones are thin to medium bedded and exhibit normal grading, although inverse to normal grading is seen rarely (Fig. F5). For example, in interval 180-1114A-7R-2, 0-53 cm, four beds of sandstone 10-25 cm thick grade upward from medium- to fine-grained sandstone, then to siltstone, and then to claystone at the top. Where visible, the bases of individual beds are sharp (e.g., 180-1114A-12R-1, 54 cm).

Most of the sandstones are structureless, but planar lamination is occasionally present, especially in the lower part of individual graded sandstones (e.g., intervals 180-1114A-9R-2, 20-76 cm; 12R-1, 0-5.5 cm; and 12R-1, 56-75.5 cm; see Fig. F6). Exceptionally, convolute lamination was noted, followed abruptly by low-angle planar lamination (intervals 180-1114A-11R-CC, 15-24 cm, and 23R-1, 49-69 cm; see Fig. F7). The base of this particular bed is sharp. In addition, small (3 cm × 1 cm) shale rip-up clasts were locally noted in the upper part of the succession (interval 180-1114A-13R-1, 61-102 cm).

The sandstone is weakly (e.g., interval 180-1114A-7R-1, 8-11 cm) to strongly (e.g., interval 180-1114A-8R-1, 15-34 cm) bioturbated in places. Individual burrows are commonly sand filled. Fragments or laminae rich in woody organic matter are locally abundant within sand beds in the upper part of the unit (intervals 180-1114A-7R-2, 0-33 cm; 8R-1, 0-11 cm; 9R-1, 53.5 cm; and 11R-1, 26.5-27.5 cm). Lower in the unit organic-rich matter was rarely observed (e.g., intervals 180-1114A-15R, 100-110 cm, and 21R-1, 33-49 cm).

Scattered benthic foraminifers were rarely observed (intervals 180-1114A-12R-1, 65-75.5 cm, and 15R-2, 0-35 cm). Within a few intervals, relatively coarse grained volcaniclastic material, especially red altered grains (e.g., intervals 180-1114A-9R-2, 0-34 cm and 71-76.5 cm), was evident in the sandstone when viewed with a hand lens.

Smear slides of the sandstone allowed us to identify quartz, plagioclase, biotite, clay, subrounded chloritic basic volcanic rock fragments, volcanic glass, rare accessory minerals (i.e., hornblende and biotite), inorganic calcite, and foraminifers (see "Site 1114 Smear Slides"). Within single samples the volcanic glass ranges from nondevitrified glass (green and colorless; e.g., Sample 180-1114A-15R-1, 20 cm), to both fresh and devitrified glass (colorless; e.g., Sample 180-1114A-23R-1, 84 cm) to mainly devitrified glass (colorless; e.g., Sample 180-1114A-24R-3, 1 cm).

XRD analysis of the sandstone (see Table T3) reveals major amounts of plagioclase and quartz, and minor amounts of calcite, pyroxene, amphibole, chlorite, and possibly smectite. However, most of the available information on sandstone composition was provided by the study of eight thin sections from throughout Unit III (see "Site 1114 Thin Sections").

The typical sandstones are poorly sorted and contain mainly angular to subangular grains (see "Site 1114 Thin Sections"). Most of the sandstones contain a silty matrix but a few are cemented by calcite spar (e.g., interval 180-1114A-11R-CC, 18-20 cm). Sandstones in the upper part of the succession (above Core 13R) contain plagioclase, quartz, basalt, biotite, pyroxene, hornblende, rare planktonic foraminifers, calcite, opaque grains, pyrite framboids, intraclasts of micrite, plant debris, shell fragments, phosphatic grains (collophane), rare limestone lithoclasts, and rare spherulitic zeolite.

The basalt-derived material in different samples ranges from crystalline basalt with microphenocrysts of olivine (commonly flow banded) to pyroxene-phyric basalt to black glassy basalt to basalt with variolitic texture to red partly devitrified basic glass (hyaloclastite) to green chloritized basic extrusive rock and to very rare blue chlorite.

In addition, there are rare occurrences of large laths of muscovite, locally abundant polycrystalline quartz (of probable metamorphic origin), calc-schist, muscovite schist, and rare green chloritic schist (Figs. F8, F9). The white mica is commonly pleochroic (colorless to bluish). In addition, several grains of serpentinite were noted in Sample 180-1114A-12R-1, 3-4 cm, and rare grains of chromite are also present.

Based on the study of six thin sections, there is a change in the composition of the sandstones below ~110 mbsf, marked by an increased input of texturally immature sandstones with fresh basaltic lithoclasts and related phenocrysts (pyroxene and olivine). However, metamorphic-derived lithoclasts (e.g., calc-schist and serpentinite) were not observed in the underlying sandstones. Otherwise, the composition is generally similar to the sandstone described above (e.g., interval 180-1114A-26R-1, 96-97 cm). Also, unlike the upper part of the succession, bioclasts are locally abundant and include coral, shell fragments, calcareous algae, bryozoans, and benthic foraminifers (e.g., Sample 180-1114A-22R-1, 74-76 cm). Small rounded lithoclasts of partly recrystallized limestone are also present (in the last-mentioned sample). Several sandstones from low in the succession are very poorly sorted with angular, broken mineral grains. Also, relatively rare acidic grains (Figs. F8, F9) are present in addition to mainly basaltic ones.

Siltstone

Siltstone is present as interbeds between sandstone and claystone and forms the upper part of graded sand beds. Siltstone is structureless or rarely planar laminated (e.g., interval 180-1114A-11R-2, 44-49 cm). In a few intervals, the siltstone is present as very thin (<3 cm) normal-graded couplets of thickly to thinly laminated siltstone passing into claystone (Fig. F10). Each of the graded couplets exhibits a sharp base with traces of scouring. Rare bioturbation is present in the overlying claystone.

In smear slides, the following constituents are seen: quartz, plagioclase, biotite, clay, volcanic rock fragments (basic and acidic), volcanic glass, opaque mineral grains, pyrite, and common inorganic carbonate grains, together with rare foraminifers and nannofossils (see "Site 1114 Smear Slides"), and occasional sponge spicules. Quartz grains are rarely observed to be undulose. Foraminifer tests from lower in the succession are pyrite filled. Several samples are sufficiently rich in plagioclase to be termed (fine grained) arkose. A thin section of a relatively well sorted siltstone (Sample 180-1114A-22R-1, 74-76 cm) contains subangular grains of quartz, plagioclase, common small muscovite laths, biotite (kinked), green chlorite, polycrystalline quartz, pyroxene, green chloritic grains, rare fragments of calcareous algae, and minute volcanic-derived grains (see "Site 1114 Thin Sections").

XRD analysis of siltstone reveals the presence of plagioclase, quartz, calcite, chlorite, and possibly smectite (see Table T3). In addition, one thin section of cross-bedded siltstone was studied (Sample 180-1104A-22R-1, 74-76 cm). This is quite well sorted and includes mainly angular grains of quartz, plagioclase, and muscovite (as minute laths), as well as rare grains of volcanic rock, biotite (as kinked laths), chloritic material, pyroxene, polycrystalline quartz, and rare calcareous algae.

Claystone

Subordinate dark gray claystone is found between the sandstones and siltstones. The claystone is mainly weakly burrowed to well burrowed (intervals 180-1114A-23R-1, 26-45 cm; and 9R-CC, 0-4.5 cm). The clay is only weakly lithified, especially where present between graded sandstones (e.g., interval 180-1114A-11R-1, 36.5-52.5 cm). Relative to sandstone, clay is very subordinate, especially in the lower part of the succession and was commonly recovered only as angular fragments (i.e., drilling breccia; e.g., Section 21R-CC).

Smear slides of the claystone ("Site 1114 Smear Slides") reveal quartz, plagioclase, biotite, clay, rare minute volcanic rock fragments, volcanic glass, pyrite, inorganic calcite, accessory minerals, poorly preserved nannofossils, and rare planktonic foraminifers. XRD analysis indicates the presence of major amounts of quartz and plagioclase and variable, mainly minor, amounts of calcite, amphibole, pyroxene, and illite (Table T3).

Subunit IIIA

Description: calcite-cemented siltstone and sandstone, packstone mainly composed of bioclasts
Interval: Sections 180-1114A-14R-1, 80 cm, through 15R-CC
Depth: 123.2-141.6 mbsf

Subunit IIIA is restricted to minor recovery in only Cores 14R and 15R. It is distinguished by the occurrence of texturally mature relatively coarse grained, calcite-cemented sandstone, siltstone, and rare bioclastic limestone.

Calcite-Cemented Sandstone

This sandstone is poorly sorted with scattered bioclasts and intra-clasts of dark siltstone. In the middle part of Subunit IIIA inverse to normal grading was occasionally observed (e.g., interval 180-1114A-15R-1, 39-48 cm). The sediments are fine to medium grained at the base and then change to coarse and very coarse grained, and then back to medium grain size at the top of the bed. The sand is rich in shell fragments, quartz, feldspar, and rock fragments (Fig. F11). The composition is one of mixed carbonate and volcaniclastic grains, including coral, calcareous algae, and shell fragments together with detrital grains. Subangular lithoclasts (<2 mm) of altered volcanic rocks are also present. The intraclasts and bedding are nearly vertical as a result of tectonic deformation (see "Structural Geology").

Two thin sections revealed a composition that is very similar to that of the adjacent sandstones of Unit III above and below (see Fig. F12), but the texture of the sandstones in Subunit IIIA differs markedly. It is characterized by well-rounded clasts and abundant carbonate bioclasts derived from a shallow-water setting. Sample 180-1114A-14R-1, 106-108 cm, is dominated by well-rounded grains of basalt together with quartz, zoned plagioclase, amphibole, acidic extrusive grains, and rare brown glass (see "Site 1114 Thin Sections"). The bioclasts are calcareous algae, echinoderm plates, shell fragments, coral, and benthic foraminifers. The sediment is well cemented by calcite spar.

Sandy Limestone (Packstone)

Two small pieces of well-cemented bioclastic sandy limestone were recovered in the core catcher of Section 14R-CC. The bioclasts are very poorly sorted and comprise calcareous algae, coral fragments, echinoderm plates and spines, and foraminifers. Numerous grains (<2 mm in size) of very altered volcanic rock and several (similar sized) elongate siltstone rip-up clasts are present.

Subunit IIIB

Description: conglomerate and sandstone
Interval: 180-1114R-20R-1, 0-60 cm
Depth: 180.1-180.7 mbsf

Subunit IIIB consists of minor granule conglomerate and sandstone that are present only in the interval 180-1114A-20R-1, 0-60 cm.

Granule Conglomerate

The conglomerate consists of angular clasts up to 0.9 cm long set in a matrix of coarse-grained sandstone. Texturally, the sediment is poorly sorted. The clasts show a very vague subhorizontal alignment. Clasts are mainly volcanic (dark basalt) with a few white carbonate bioclasts. The sandstones in the cores above and below interval 180-1114A-20R-1, 0-60 cm, are of similar composition to those of the present subunit. This subunit is thus recognized only on the basis of the presence of gravel-sized clasts.

Interpretation

Unit III, as well as Subunit IIIA, records variable deposition from turbidity currents in a middle bathyal setting during middle-late Pliocene time (see "Biostratigraphy"). The normal grading is suggestive of deposition from decelerating currents. Burrowing is present but rarely well developed, suggesting that bottom conditions were possibly suboxic but not reducing. However, beneath the seafloor fully anoxic conditions were probably developed during deposition of the whole of Unit III, as suggested by the subdued colors and common abundance of organic matter of mainly terrestrial origin (i.e., woody material), locally elevated contents of organic carbon (up to 1.4%; see "Organic Geochemistry"), and common pyrite. Subunit IIIA records deposition of sediment ultimately derived from a shallow-water depositional setting (see "Depositional History" for further discussion). In addition, the granule conglomerates are interpreted as deposits from high-density turbidity currents (Pickering et al., 1989).

The provenance of Unit III was from a volcanic arc-type terrane, including a range of basic, andesitic, and vitric volcanics. It is notable that the provenance of the detrital component of the fine-, medium-, and coarse-grained sediments is very similar. This suggests that the sediment was derived relatively locally from within a single basin and was not derived from different source areas. The presence of variolitic textured basalt suggests that some of the basalts were extruded subaqueously. On the other hand, volcanic glass is relatively minor and typically altered, suggesting that explosive subaerial (or near subaerial) volcanism is not greatly represented. Many of the volcaniclastic-rich sandstones are texturally immature. Samples from near the base include unaltered glassy basalt and olivine, suggesting that the volcanic material was eroded rapidly and redeposited without significant subaerial weathering.

In addition, the rare muscovite laths, strongly recrystallized (polycrystalline) quartz, rare calc-schist, and very fine grains of mica schist are inferred to have been derived from a low-grade metamorphosed volcanic terrane.

The geophysical and FMS logs support the above interpretation (see "Downhole Measurements"). Only features interpreted as being of primary stratigraphic significance are mentioned here; details of the structural features including the evidence for the dip of bedding, location, and orientation of fractures are presented in "Structural Geology". From the top of the logged interval (~96 mbsf) to 125 mbsf (near the top of Subunit IIIA), the response on most logs is similar and is interpreted to reflect relatively uniform deposition of claystone, siltstone, and sandstone. The FMS images indicate well-developed layering with thin sandstones ~10 cm thick standing out as resistive layers. Around 120-140 mbsf, the gamma-ray and resistivity logs peak, suggesting that more sandy beds may be present, possibly correlating with Subunit IIIA. From 113 to 118 mbsf, possible cross bedding is present. At 125 mbsf, the hole conditions deteriorated and the FMS images are more difficult to interpret.

The photoelectric effect and the corrected limestone porosity log show a highly variable response between 142.5 and 200 mbsf (with 11 major peaks ~2 m thick and 12 smaller peaks ~1 m thick). This overall interval includes Subunit IIIA composed of calcite-cemented siltstone, sandstone, and packstone in which calcium carbonate content is elevated (up to 4.6 wt% and locally higher, based on other smear-slide observations). However, the amplitude of these peaks is considered to be too great to be explicable by increased calcium carbonate content alone, even if limestone was present but not recovered (see "Downhole Measurements"). Instead, the variable photoelectric effect could correlate with the presence of reduced iron minerals (e.g., pyrite, marcasite, or siderite). XRD analysis indicated a single occurrence of marcasite but at a greater depth (~240 mbsf; see Table T3). In addition, pyrite was commonly observed in the cores and smear slides.

A small peak in resistivity at 177.5 mbsf, equivalent to a position near the top of Subunit IIIA, may indicate the presence of a thin sandstone interval. Variably sandy intervals appear to be present from 128 to 177 mbsf. From 179 to 181.5 mbsf, there is a distinctly resistive interval that may correlate with relatively coarse grained sandstone making up Subunit IIIB. The Th/U ratio reaches a maximum at this depth and may indicate high input of relatively radiogenic volcaniclastic sandstone. This interval could also contain U-rich organic matter derived from a shallow-water setting by mass flow processes. There is then an interval of low resistivity from 223 to 228 mbsf that correlates with an enlarged caliper located within the lower part of Unit III (beneath Subunit IIIB). One other feature is the presence of a tight-limbed fold observed in the cores from ~208 mbsf that could possibly represent a slump fold, although a tectonic origin (i.e., deformation of sediment while still soft) cannot be ruled out (see "Structural Geology").

Lithostratigraphic Unit IV

Description: fine- to coarse-grained sandstone
Interval: Cores 180-1114A-26R through 29R
Depth: 237.6-276.1 mbsf
Age: middle to late Pliocene

The unit is predominantly sandstone that is distinguished from Unit III mainly by a change from a grayish to a dusky red brown color. Individual sandstone intervals vary from well lithified to less well lithified.

Sandstone

The sandstone is fine to coarse grained and ranges from weakly lithified to well lithified. It is mainly fine to medium grained, but is rarely coarse grained with scattered granules up to 4 mm in size (e.g. interval 180-1114A-29R-CC, 0-7.5 cm). Unfortunately, the recovery of these sandstones was minimal, and it is not possible to specify information including bed thickness and the nature of contacts.

Smear slides of the less lithified material (see "Site 1114 Smear Slides") revealed quartz and plagioclase, together with rare biotite, clay, volcanic rock fragments (see Fig. F13), devitrified volcanic glass, accessory minerals, calcite rhombs, and foraminifers (see "Site 1114 Smear Slides"). XRD analysis confirmed the presence of major amounts of plagioclase and minor quartz, pyroxene, and amphibole. In addition, very minor claystone was seen in XRD to contain quartz, plagioclase, calcite, and minor pyrite, marcasite, chlorite, possible smectite, illite, and amphibole (see Table T3).

Two thin sections of sandstone from Unit IV were studied (see Fig. F13). One was present only a few centimeters above the tectonic breccia forming Unit VI (see "Lithostratigraphic Unit VI"). This is similar to the sandstones higher in the succession and includes plagioclase, clinopyroxene, lithoclasts of clinopyroxene-phyric basalt, variolitic basalt, devitrified basic glass (hyaloclastite), minor acidic volcanics, and rare polycrystalline quartz (altered acidic volcanic rock?), chloritic grains, and organic material.

Interpretation

Unfortunately, there is inadequate information on sedimentary characteristics and paleobathymetry to specify the mode of deposition. It is assumed, however, that the sandstones record very similar deposition by turbidity currents as in Unit III, and a similar provenance from a calc-alkaline type volcanic arc terrane is inferred, including unaltered volcanic rocks.

Below 233 mbsf, the hole conditions were generally poor and FMS images are difficult to interpret (see "Downhole Measurements"). Unit IV includes a zone of faulting (see "Structural Geology"). Locally, at ~249 mbsf, an interval of low resistivity may correlate with the presence of strongly altered dusky red sandstones in the cores.

Lithostratigraphic Unit V

Description: silty claystone
Interval: Core 180-1114A-30R through Section 31R-1, 25 cm
Depths: 276.1-286.05 mbsf
Age: middle to late Pliocene

This unit is restricted to silty claystone with minor siltstone and sandstone. The fine grain size contrasts strongly with the overlying coarse-grained sandstone of Unit IV. This unit is only weakly lithified in places. It is also strongly deformed (see "Structural Geology"), which inhibits sedimentological analysis.

Silty Claystone, Calcareous Silt, and Clay

The silty claystone and fine-grained sandstone are highly deformed, and few primary sedimentary structures can be discerned other than several thin, sharp-based interbeds of fine-grained sandstone (<10 cm thick; see Fig. F14).

In smear slide, the calcareous silt contains quartz, plagioclase, biotite, clay, accessory minerals (hornblende), inorganic calcite, rare nannofossils, and sponge spicules (see "Site 1114 Smear Slides"). A sample of calcareous clay is similar in composition and includes numerous inorganic calcite crystals. Associated clay contains major amounts of plagioclase, quartz, and minor smectite?, chlorite, and pyroxene.

One sandstone bed (interval 180-1114A-30R-CC, 0-22 cm) is composed of angular and rounded fragments of claystone and siltstone (2-3 mm); these are very strongly deformed and brecciated, and are set in a fine- to medium-grained, poorly sorted matrix. A smear slide of the sandstone revealed an arkosic composition marked by common plagioclase, altered volcanic rock fragments (including basalt; Fig. F15), accessory minerals (pyroxene, hornblende), rare quartz, and inorganic calcite. A thin section of the sandstone indicates it contains grains of quartz, feldspar, pyroxene, epidote, biotite, hornblende, variolitic basalt, acidic volcanics, dolerite, and carbonaceous material (see "Site 1114 Thin Sections"). XRD analysis of the sandstone revealed major amounts of plagioclase and quartz, and minor chlorite, smectite?, and pyroxene (Table T3).

The base of Unit V is composed of only weakly indurated brown clay (interval 180-1114A-31R-1, 0-15 cm) within thin (several millimeters), weakly indurated silt laminae and secondary color mottling.

Interpretation

Unit V records a period of mainly fine-grained deposition with only very subordinate siltstones and sandstones deposited by turbidity currents. The composition of rare sandstones remains similar to that of the sandstones of Unit IV without a trace of lithologies derived from the local metamorphic basement (see "Igneous and Metamorphic Petrology").

Lithostratigraphic Unit VI

Description: tectonic breccia
Interval: Sections 180-1114A-31R-1, 25 cm, through 31R-CC
Depth: 286.05-287.35 mbsf
Age: middle to late Pliocene

Unit VI is a thin but distinctive interval of tectonic breccia that separates the sediments of Unit V above from metamorphic rocks beneath (Unit VII). The unit is subdivided into two parts.

The upper part of the unit is a breccia (interval 180-1114A-31R-1, 25-74 cm) composed of angular to subangular clasts of greenschist, <0.6 cm in size, set in a greenish matrix that also includes scattered, well- rounded grains (red, brown, and colorless). A crude layering is present but without any recognizable sedimentary structures or bedding planes.

A smear slide of the matrix contains quartz, plagioclase, clay, accessory minerals, opaque grains, and inorganic calcite. A thin section revealed an unusual texture and composition. The greenish silty matrix contains subrounded grains of chlorite/actinolite schist and altered dolerite.

The lower part of the unit is a contrasting type of breccia (intervals 180-1114A-31R-1, 74-130 cm, and 31R-CC, 0-18 cm) that is composed of weakly indurated angular clasts (<1 cm in size) of finely crystalline, very altered greenschist set in a greenish silty matrix. Careful inspection did not reveal the presence of any sedimentary grains. In places, relict altered veins are present that can be traced through the body of the rock. Patchy yellow/brown alteration is also present (on a scale of several centimeters).

A smear slide was found to contain quartz, plagioclase, biotite, clay, accessory minerals, and inorganic calcite. A thin section exhibits brecciated actinolite schist, with angular clasts and evidence of veining and partial silicification. This material is similar in lithology to the underlying "basement" (see "Igneous and Metamorphic Petrology"). In addition, a vein infill contains major amounts of plagioclase, calcite, kaolinite, smectite?, and minor quartz (Table T3).

Interpretation

The breccia is tectonic in origin, and no sedimentary constituents associated with the overlying succession were identified. The upper unit (interval 180-1114A-31R-1, 25-74 cm) contains numerous angular, to subangular, to subrounded clasts of altered metamorphic rock. The more rounded grains are not interpreted as sedimentary grains. More probably they are fragments of tectonic breccia that were subrounded by shearing associated with faulting. On the other hand, the lower unit (intervals 180-1114A-31R-1, 74-130 cm, and 31R-CC, 0-18 cm) includes a vein fabric that although altered and deformed, is seen as being inherited from the underlying metamorphic basement. In addition, an unusual occurrence of kaolinite within the veins of the tectonic breccia may relate to low-temperature hydrothermal alteration of the intrusive basement rocks. The presence of chloritized vein fills also suggests that hydrothermal alteration played an important role.

An interval of ~287.7-292 mbsf corresponding to the tectonic breccia is imaged on the FMS as a dark, conductive interval (see "Downhole Measurements"). The image is similar to the shear zones located at the Unit IV/Unit V boundary and suggests that only part of this fault breccia was recovered. Little textural or other structural information could be gained because of the insufficient quality of the data, most likely owing to enlarged hole diameters. However, there is a big increase in resistivity at 292 mbsf, which corresponds to the contact between Unit VI and the metamorphic basement beneath. This contact is sharp and dips at ~40º to the southwest subparallel to the inferred orientation of the fault zone on seismic profiles (see "Downhole Measurements").

Lithostratigraphic Unit VII

Description: metadolerite (greenschist facies)
Interval: Cores 180-1114A-32R through 37R
Depth: 295.4-352.8 mbsf

Lithostratigraphic Unit VII is composed of metadolerite that is brecciated and contains quartz, calcite, and epidote veins. This unit is described in detail in "Igneous and Metamorphic Petrology".

Depositional History

The geophysical and FMS log data help to fill major gaps in the recovery and are interpreted to suggest that the succession as a whole consists of alternating sandy and silty/clayey sediments with a maximum of sand ~180 mbsf corresponding to Subunit IIIB, then becoming generally more silty downward.

Sedimentation at Site 1114 records rapid rift-related volcaniclastic deposition that can only be dated as middle-late Pliocene in age. Almost the entire succession was deposited by redepositional processes including turbidity currents of variable concentrations in an upper bathyal setting (150-500 m; see "Biostratigraphy"). The recorded succession began with an interval of relatively fine grain size (Unit V). The origin of the overlying dusky red sandstones of Unit V is unclear, but could relate to (oxidative) diagenesis (i.e., related to fluid flow within the sediment), and may thus not reflect primary depositional characteristics. Unit III preserves relatively monotonous turbidity current deposits that rarely reached conglomerate size (i.e., granule conglomerate of Subunit IIIB).

In addition, there was a single interval of sandstone and rare packstone, Subunit IIIA, that was deposited by turbidity currents. These include abundant shallow-water derived fossils and well-rounded clasts of basalt and other volcanic rocks. These sediments record an unusual supply of sand from a high-energy littoral source (i.e., coastal or shoal).

The accumulation of coarse-grained sediments is probably related to turbidity currents that changed to deposition of fine-grained sediments. There was then a dramatic change from the well-lithified clastic sedimentary rocks of Units II through IV to superficial Quaternary clay-bearing nannofossil ooze. The probable explanation of the strong difference in lithification state is that at least several hundred meters of the sediments was deposited and then removed, presumably by current activity (i.e., winnowing), slumping, or tectonic processes resulting from the uplift of the seamount. The hiatus in the sedimentary record is reflected by the absence of micropaleontologic Subzones NN19E-F (see "Biostratigraphy"). Removal of at least 165 m is inferred from the porosity vs. depth relationship of the sediment of Site 1114 (see "Physical Properties"). This was followed by pelagic and hemipelagic deposition in a setting removed from clastic sediment input, which probably occurred after uplift of the Moresby Seamount to near its present position.

Throughout the deposition of sand and sandstone at Site 1114 derivation was from a calc-alkaline-type volcanic terrane. Volcaniclastic sediments were probably eroded from the Miocene Trobriand Arc (including Amphetts Island and Egum Atoll) (Lock et al., 1987; Davies et al., 1987). This arc was uplifted during rifting of the Woodlark Basin in the Pliocene or earlier (Goodliffe et al., 1993). The volcanic arc was not deeply eroded at this stage because plutonic rock detritus is rare or absent. On the other hand, the unusual grains of muscovite, calc-schist, locally abundant polycrystalline quartz and rare serpentinite, and zircon are inferred to have been derived from an ultramafic ophiolitic terrane and metamorphic basement, as exposed in the D'Entrecasteaux Islands and southeastern Papua New Guinea (Davies, 1980; Davies and Warren, 1988). The metamorphic debris and ophiolite-derived grains are present mainly above 125 mbsf and may thus be related to rift faulting and uplift of metamorphic basement in the vicinity of the Moresby Seamount.

After deposition, the entire sedimentary succession, except the thin, surficial sediments of Quaternary age, experienced faulting concentrated within discrete zones (see "Structural Geology"). It is assumed that this deformation relates to uplift of the Moresby Seamount. If this is correct, then the uplift probably took place between late Pliocene and Pleistocene deposition of Unit II and Pleistocene accumulation of Unit I. In detail, the absence of nannofossil Subzones NN19E and NN19F (see "Biostratigraphy"), in contrast to a continuous stratigraphic record from Subzone NN19B downward within the talus derived from the Moresby Seamount (see "Biostratigraphy"  in the "Sites 1110-1113" chapter), suggests that uplift of the seamount took place between 0.46 Ma (top of Subzone NN19F) and ~1.67 Ma (base of Subzone NN19E).

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