Table T2. Complete analytical data set for massive and semimassive sulfides.

Table T2. Complete analytical data set for massive and semimassive sulfides.


CSIRO number	Element:	Li	Be	Na	Na	Mg	Al	Si	P	S	K	K	Ca	Ca
	Method:	ICP-AES	ICP-AES	ICP-AES	INAA	ICP-AES	ICP-AES	ICP-AES*	ICP-AES	ICP-AES	ICP-AES	INAA	ICP-AES	INAA
	Unit:	(ppm)	(ppm)	(ppm)	(wt%)	(ppm)	(ppm)	(ppm)	(ppm)	(ppm)	(ppm)	(wt%)	(ppm)	(wt%)
	DL:	5	2		0.01				50		50	0.2		0.5
142701		2.2	0.2	1,305		1,850	12,946	170,907	9	274,664	5,966		3,951
142703		0.8	0.1	227	0.04	2,794	1,680	5,690	ND	361,547	ND	<0.2	91,275	9.8
142705		2.6	0.2	67		78	1,716	272,319	359	202,880	342		856
142807		16.9	0.2	2,295	0.25	2,954	22,012	40,356	187	366,125	9,149	0.9	15,533	1.9
142808		0.1	0.1	315	0.05	608	1,186	6,326	ND	509,130	481	<0.2	188	<0.5

CSIRO
number

Element:

Sc

Sc

Sc

Ti

V

V

Cr

Cr

Cr

Mn

Fe

Fe

Co

Method:

ICP-AES

ICP-MS

INAA

ICP-AES

ICP-AES

ICP-MS

ICP-AES

ICP-MS

INAA

ICP-AES

ICP-AES

INAA

ICP-AES

Unit:

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(wt%)

(ppm)

DL:

5

100

0.1

5

5

10

142701 2.3 2,390 905 30 28,423 2 4,400 43 234,331 620

142703 ND 156 0.4 48 2 2,374 ND 1,053 <10 73 254,353 27 73

142705 ND 81 24 2 4,530 2 6,927 101 188,821 60

142807 2.3 3,312 4.6 1,189 23 20,500 46 47,360 57 282 300,729 32 93

142808 ND 545 0.4 56 1 1,315 ND 1,181 <10 209 439,006 47 95

CSIRO number	Element:	Sc	Sc	Sc	Ti	V	V	Cr	Cr	Cr	Mn	Fe	Fe	Co
Method:	ICP-AES	ICP-MS	INAA	ICP-AES	ICP-AES	ICP-MS	ICP-AES	ICP-MS	INAA	ICP-AES	ICP-AES	INAA	ICP-AES
Unit:	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(wt%)	(ppm)
DL:	5	100	0.1		5		5		10
142701		2.3	2,390		905	30	28,423	2	4,400		43	234,331		620
142703		ND	156	0.4	48	2	2,374	ND	1,053	<10	73	254,353	27	73
142705		ND	81		24	2	4,530	2	6,927		101	188,821		60
142807		2.3	3,312	4.6	1,189	23	20,500	46	47,360	57	282	300,729	32	93
142808		ND	545	0.4	56	1	1,315	ND	1,181	<10	209	439,006	47	95

CSIRO
number

Element:

Co

Co

Ni

Ni

Cu

Zn

Zn

Ga

Ge

As

As

As

Se

Method:

ICP-MS

INAA

ICP-AES

ICP-MS

ICP-AES

ICP-AES

INAA

ICP-MS

ICP-MS

ICP-AES

ICP-MS

INAA

INAA

Unit:

(ppb)

(ppm)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(ppb)

(ppb)

(ppm)

(ppb)

(ppm)

(ppm)

DL:

10

100

142701 OR 12 10,570 32,267 232 11,516 6,191 89 79,758

142703 66,140 80 ND 2,854 50,423 638 640 1,100 5,481 231 217,900 741 42

142705 56,083 10 7,651 114 276 405 3,721 271 OR

142807 81,655 95 34 30,055 15,801 16,394 18,100 12,855 10,525 269 256,550 1,020 47

142808 80,830 98 ND 1,253 1,142 451 507 649 8,060 204 191,000 629 78

CSIRO number	Element:	Co	Co	Ni	Ni	Cu	Zn	Zn	Ga	Ge	As	As	As	Se
Method:	ICP-MS	INAA	ICP-AES	ICP-MS	ICP-AES	ICP-AES	INAA	ICP-MS	ICP-MS	ICP-AES	ICP-MS	INAA	INAA
Unit:	(ppb)	(ppm)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(ppb)	(ppb)	(ppm)	(ppb)	(ppm)	(ppm)
DL:			10				100
142701		OR		12	10,570	32,267	232		11,516	6,191	89	79,758
142703		66,140	80	ND	2,854	50,423	638	640	1,100	5,481	231	217,900	741	42
142705		56,083		10	7,651	114	276		405	3,721	271	OR
142807		81,655	95	34	30,055	15,801	16,394	18,100	12,855	10,525	269	256,550	1,020	47
142808		80,830	98	ND	1,253	1,142	451	507	649	8,060	204	191,000	629	78

CSIRO
number

Element:

Br

Rb

Rb

Sr

Y

Y

Zr

Zr

Mo

Mo

Mo

Ag

Ag

Method:

INAA

ICP-MS

INAA

ICP-AES

ICP-AES

ICP-MS

ICP-AES

INAA

ICP-AES

ICP-MS

INAA

ICP-AES

INAA

Unit:

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

DL:

1

20

2

5

500

5

5

142701 8,252 10 3.4 961 15 65 64,042 1.3

142703 1 265 21 574 0.8 943 9 <500 70 75,580 69 2.5 <5

142705 647 13 1.1 778 4 76 76,029 0.7

142807 12 14,985 44 199 2.2 2,298 17 <500 68 74,125 65 14.8 13.2

142808 3 1,059 22 5 0.3 428 8 <500 41 45,730 42 1.3 <5

CSIRO number	Element:	Br	Rb	Rb	Sr	Y	Y	Zr	Zr	Mo	Mo	Mo	Ag	Ag
Method:	INAA	ICP-MS	INAA	ICP-AES	ICP-AES	ICP-MS	ICP-AES	INAA	ICP-AES	ICP-MS	INAA	ICP-AES	INAA
Unit:	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)
DL:	1		20		2		5	500				5	5
142701			8,252		10	3.4	961	15		65	64,042		1.3
142703		1	265	21	574	0.8	943	9	<500	70	75,580	69	2.5	<5
142705			647		13	1.1	778	4		76	76,029		0.7
142807		12	14,985	44	199	2.2	2,298	17	<500	68	74,125	65	14.8	13.2
142808		3	1,059	22	5	0.3	428	8	<500	41	45,730	42	1.3	<5

CSIRO
number

Element:

Cd

Cd

Cd

In

Sb

Sb

Sb

Te

Te

Cs

Cs

Ba

Ba

Method:

ICP-AES

ICP-MS

INAA

ICP-MS

ICP-AES

ICP-MS

INAA

ICP-MS

INAA

ICP-MS

INAA

ICP-AES

INAA

Unit:

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

DL:

5

20

50

0.2

90

10

10

2

100

142701 5 576 771 8 2,732 71,728 71 286

142703 7 1,826 <20 2,802 14 5,506 4.9 168 <10 9 <2 78 118

142705 ND 1,187 276 13 3,522 5,566 60 100

142807 64 56,825 81 4,244 59 47,170 48.1 4,856 <10 187 <2 101 10,400

142808 6 887 <20 436 21 2,041 1.4 3,613 <10 64 <2 145 206

CSIRO number	Element:	Cd	Cd	Cd	In	Sb	Sb	Sb	Te	Te	Cs	Cs	Ba	Ba
Method:	ICP-AES	ICP-MS	INAA	ICP-MS	ICP-AES	ICP-MS	INAA	ICP-MS	INAA	ICP-MS	INAA	ICP-AES	INAA
Unit:	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)
DL:	5		20		50		0.2	90	10	10	2		100
142701		5	576		771	8	2,732		71,728		71		286
142703		7	1,826	<20	2,802	14	5,506	4.9	168	<10	9	<2	78	118
142705		ND	1,187		276	13	3,522		5,566		60		100
142807		64	56,825	81	4,244	59	47,170	48.1	4,856	<10	187	<2	101	10,400
142808		6	887	<20	436	21	2,041	1.4	3,613	<10	64	<2	145	206

CSIRO
number

Element:

La

La

La

Ce

Ce

Pr

Nd

Sm

Sm

Eu

Eu

Gd

Tb

Method:

ICP-AES

ICP-MS

INAA

ICP-MS

INAA

ICP-MS

ICP-MS

ICP-MS

INAA

ICP-MS

INAA

ICP-MS

ICP-MS

Unit:

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppb)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppb)

DL:

0.5

2

0.5

142701 4.1 4,083 9,280 1,275 5,278 966 118 749 75

142703 3.7 3,512 3.6 8,325 9 1,273 5,568 1,359 1.4 778 0.8 875 95

142705 0.7 556 1,486 250 1,319 377 194 376 48

142807 6.9 6,680 8.2 14,515 17 2,030 8,481 1,665 2.1 712 0.8 1,288 155

142808 0.5 738 0.9 1,504 2 223 1,036 222 0.4 97 <0.5 185 27

CSIRO number	Element:	La	La	La	Ce	Ce	Pr	Nd	Sm	Sm	Eu	Eu	Gd	Tb
Method:	ICP-AES	ICP-MS	INAA	ICP-MS	INAA	ICP-MS	ICP-MS	ICP-MS	INAA	ICP-MS	INAA	ICP-MS	ICP-MS
Unit:	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppb)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppb)
DL:			0.5		2						0.5
142701		4.1	4,083		9,280		1,275	5,278	966		118		749	75
142703		3.7	3,512	3.6	8,325	9	1,273	5,568	1,359	1.4	778	0.8	875	95
142705		0.7	556		1,486		250	1,319	377		194		376	48
142807		6.9	6,680	8.2	14,515	17	2,030	8,481	1,665	2.1	712	0.8	1,288	155
142808		0.5	738	0.9	1,504	2	223	1,036	222	0.4	97	<0.5	185	27

CSIRO
number

Element:

Dy

Ho

Er

Tm

Yb

Yb

Yb

Lu

Lu

Hf

Ta

W

Ir

Method:

ICP-MS

ICP-MS

ICP-MS

ICP-MS

ICP-AES

ICP-MS

INAA

ICP-MS

INAA

INAA

INAA

INAA

INAA

Unit:

(ppb)

(ppb)

(ppb)

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppm)

(ppm)

(ppm)

(ppm)

(ppb)

DL:

2

0.5

0.2

1

1

2

20

142701 254 40 88 9 0.3 87 14

142703 379 46 89 5 ND 30 <0.5 7 <0.2 <1 <1 <2 <20

142705 226 35 104 9 ND 56 8

142807 620 100 235 24 ND 148 0.9 20 <0.2 1.1 <1 11 <20

142808 88 22 41 9 ND 25 <0.5 5 <0.2 <1 <1 <2 <20

CSIRO number	Element:	Dy	Ho	Er	Tm	Yb	Yb	Yb	Lu	Lu	Hf	Ta	W	Ir
Method:	ICP-MS	ICP-MS	ICP-MS	ICP-MS	ICP-AES	ICP-MS	INAA	ICP-MS	INAA	INAA	INAA	INAA	INAA
Unit:	(ppb)	(ppb)	(ppb)	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppm)	(ppm)	(ppm)	(ppm)	(ppb)
DL:					2		0.5		0.2	1	1	2	20
142701		254	40	88	9	0.3	87		14
142703		379	46	89	5	ND	30	<0.5	7	<0.2	<1	<1	<2	<20
142705		226	35	104	9	ND	56		8
142807		620	100	235	24	ND	148	0.9	20	<0.2	1.1	<1	11	<20
142808		88	22	41	9	ND	25	<0.5	5	<0.2	<1	<1	<2	<20

CSIRO
number

Element:

Au

Hg

Tl

Pb

Pb

Bi

Th

Th

U

U

Method:

INAA

INAA

ICP-MS

ICP-AES

ICP-MS

ICP-MS

ICP-MS

INAA

ICP-MS

INAA

Unit:

(ppb)

(ppm)

(ppb)

(ppm)

(ppb)

(ppb)

(ppb)

(ppm)

(ppb)

(ppm)

DL:

5

5

5

0.5

2

142701 5,020 112 77,947 36,211 392 687

142703 858 5 33,160 104 78,220 15,450 8 <0.5 441 <2

142705 116,356 187 158,020 33,788 11 155

142807 1,970 6 41,000 491 OR 14,470 159 <0.5 2,460 2.7

142808 1,990 9 27,250 115 109,200 17,610 31 <0.5 783 <2

CSIRO number	Element:	Au	Hg	Tl	Pb	Pb	Bi	Th	Th	U	U
Method:	INAA	INAA	ICP-MS	ICP-AES	ICP-MS	ICP-MS	ICP-MS	INAA	ICP-MS	INAA
Unit:	(ppb)	(ppm)	(ppb)	(ppm)	(ppb)	(ppb)	(ppb)	(ppm)	(ppb)	(ppm)
DL:	5	5					5	0.5		2
142701				5,020	112	77,947	36,211	392		687
142703		858	5	33,160	104	78,220	15,450	8	<0.5	441	<2
142705				116,356	187	158,020	33,788	11		155
142807		1,970	6	41,000	491	OR	14,470	159	<0.5	2,460	2.7
142808		1,990	9	27,250	115	109,200	17,610	31	<0.5	783	<2

Notes: CSIRO = Commonwealth Scientific and Industrial Research Organisation, ICP-AES = inductively coupled plasma–atomic emission spectroscopy, ICP-MS = inductively coupled plasma–mass spectrometry, INNA = instrumental neutron activation analysis. DL = detection limit (cited where close to or exceeding some values). ND = not detected, OR = over range. Sample 142807 had a white residue present on dissolution; S, Ba, and Pb may be underestimated in ICP data, * = closed-vessel dissolution. As by ICP-AES and ICP-MS may be underestimated at this level if As not fully oxidized during dissolution. Zr data by ICP-AES may be unreliable at this level. See Table T1 for ODP sample identifications for CSIRO numbers.